The contrapositive of (B) reads like this:
If Selena doesn't have psychic powers, then it is impossible to have psychic powers.
The conclusion is saying, "if we find out whether Selena has psychic powers, we'll know whether it's possible to have psychic powers".
This is a "damned if you do, damned if you don't" type of Sufficient Assumption, meaning that it creates a situation where whether X is true or X is false, we get to the conclusion either way.
If we find out Selena DOES have psychic powers, then clearly we've determined whether it's possible to have psychic powers (you only need one example of it happening to determine that it's possible).
If we find out Selena DOES NOT have psychic powers, then the rule in (B) tells us that "it's impossible to have psychic powers", so we will have clearly determined whether it's possible to have psychic powers.
tl;dr version:
if she has them, we've determined it's possible to have them.
if she doesn't have them (+ the rule in B), we've determined it's impossible to have them.
So the conclusion is right! Finding out whether Selena has psychic powers will allow us to determine whether it's possible to have them.
If you want another example of a "damned if you do, damned if you don't" sufficient assumption, try this one:
https://www.manhattanprep.com/lsat/foru ... 13358.html