Applying these thoughts to those problems, note that the ozone problem doesn't give you a choice between 'had appeared' and simply 'appeared'. Here, the 'had' emphasizes that the appearing took place before the realization, but I think 'appeared' would be fine also. It's not that common to use past perfect for an event before present perfect. The more common pairing is past perfect and past simple.
Ok. Since Ist problem did not have option of simple past, use of "had appeared" is fine.
So below mentioned sentence would be fine:
Ozone reaches high concentrations twelve miles above Earth, where it appeared immune to human influence; we have now realized, though, that emissions of industrial chlorofluorocarbons deplete the ozone layer.
Not sure exactly what you mean by 'point event', but if you mean 'action that took place in the past and is now finished' then we'd need to use the past simple. If we wanted to state that the suggesting took place in the past and is finished now, we'd need to say 'Some art historians once suggested that Impressionism..
I did not get your point about above highlighted portion.
"Have + ed" means that
(a) action that took place in the past and is now finished
Tarun has completed his graduation from Harvard Business School.
Here we don't know that when has tarun completed his graduation. May be 10 years ago or recently but effect of completion is relevant to present.
Russia and the U.S. have sent expeditions to the moon. ( This event happened over forty years ago but it's relevant to the current topic of discussion)
(b) action took place till recent past but definitely not going on in present
I have lived in NYC for 2 years ( means I lived in NYC till now but now I am not living anymore)
Simple past is a past event that completed in the past and it's not relevant to present.
Tarun completed his graduation in 2008.
Kindly review my understanding.
Regards,
Rahul Singh